1-Diphenylmethylene-2-(9H-fluoren-9-ylidene)hydrazine
نویسندگان
چکیده
منابع مشابه
2-(9H-Fluoren-9-ylidenemethyl)thiophene
The title compound, C(18)H(12)S, contains a thio-phene ring which is disordered by rotation of 180° about the linking C-C bond. The site occupancies of the major and minor components of the disordered ring are 0.900 (3) and 0.100 (3), respectively. In one of these disordered components, the mol-ecule is stabilized by an intra-molecular C-H⋯S hydrogen bond. The compound was synthesized in good y...
متن کامل1-Diphenylmethylene-2-(9H-fluoren-9-ylidene)hydrazine
In the title mol-ecule, C(26)H(18)N(2), the 9H-fluorene unit is almost planar, as the cyclo-penta-diene ring makes dihedral angles of 1.12 (6) and 1.46 (6)° with the fused benzene rings. The dihedral angle between the two phenyl rings of the diphenyl-methyl-ene residue is 61.78 (6)°.
متن کامل9-Chloromethyl-9-[(9H-fluoren-9-yl)methyl]-9H-fluorene
In the title compound, C(28)H(21)Cl, the dihedral angle between the two fluorene ring systems is 71.97 (4)°. There is an intra-molecular C-H⋯Cl hydrogen bond. In the crystal structure, the centroid-to-centroid distance between stacked fluorene ring systems is ca 4.22 Å, which indicates that there are no π-π stacking inter-actions between them.
متن کامل9-Allyl-9H-fluoren-9-ol
The asymmetric unit of the title compound, C16H14O, contains two independent mol-ecules differing in the orientations of the allyl groups; the corresponding O-C-C(H2)-C(H) torsion angles are -61.01 (13) and -177.43 (10)°. In the crystal, O-H⋯O hydrogen bonds link four mol-ecules into a centrosymmetric tetra-mer, in which each hy-droxy group acts as a donor and an acceptor of hydrogen bonds.
متن کاملN-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
The title mol-ecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-tri-methyl-silyfluorenyl lithium and 2-meth-oxy-benzo-nitrile. The fluorene ring system is substanti-ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-meth-oxy-benzyl-amine ring plane. In the crystal, mol-ec...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s160053681000070x